Manganese-Rich Sandstones Point to Earth-Like Environment on Ancient Mars

In Might 2017, NASA’s Curiosity rover noticed greater than traditional quantities of manganese within the lakebed rocks inside Gale crater, Mars. These sedimentary rocks have bigger grain sizes than what’s typical for the lakebed rocks within the crater. This may occasionally point out that the unique sediments have been fashioned in a river, delta, or close to the shoreline within the historic lake. In a brand new paper, Dr. Patrick Gasda from Los Alamos Nationwide Laboratory and his colleagues focus on how manganese may have been enriched in these rocks — for instance, by percolation of groundwater via the unique sediments or via the rock afterward — and what oxidant could possibly be accountable for the precipitation of manganese within the rocks. On Earth, manganese turns into enriched due to oxygen within the environment and this course of is usually sped up by the presence of microbes. Microbes on Earth can use the various oxidation states of manganese as power for metabolism; if life was current on historic Mars, the elevated quantities of manganese in these rocks alongside the lake shore could be a useful power supply for all times.

Mastcam mosaic from the Sol 1686 rover location looking behind the rover (downslope) at the transition point between the Sutton Island and Blunts Point Murray members. Images from Sols 1685-1689 display sedimentary textures of dark-toned manganese-rich sandstones and nearby rocks. Dashed line boxes in the large mosaic are shown as insets along the bottom of figure. Small red outlines show the approximate locations and extent of ChemCam observations. Throughout this transition area, dark-toned sandstones (presumably manganese-rich based on ChemCam observations at three locations) overlie light-toned materials. Insets from left to right: (a) Denning Brook, a manganese-rich fine-grained dark-toned sandstone ChemCam observation; (b) and (c) two light-toned blocks with cross-stratified textures, highlighted with yellow lines, 6 m away from Denning Brook and to the upper left in the large mosaic; (d) dark-toned materials (center of mosaic); and (E1) Newport Ledge, (E2) AEGIS post 1685a, (E3) Sugarloaf Mountain, three thin planar laminated dark-toned sandstones. Image credit: NASA / Caltech-JPL / MSSS.

Mastcam mosaic from the Sol 1686 rover location trying behind the rover (downslope) on the transition level between the Sutton Island and Blunts Level Murray members. Photos from Sols 1685-1689 show sedimentary textures of dark-toned manganese-rich sandstones and close by rocks. Dashed line containers within the massive mosaic are proven as insets alongside the underside of determine. Small crimson outlines present the approximate areas and extent of ChemCam observations. All through this transition space, dark-toned sandstones (presumably manganese-rich primarily based on ChemCam observations at three areas) overlie light-toned supplies. Insets from left to proper: (a) Denning Brook, a manganese-rich fine-grained dark-toned sandstone ChemCam commentary; (b) and (c) two light-toned blocks with cross-stratified textures, highlighted with yellow strains, 6 m away from Denning Brook and to the higher left within the massive mosaic; (d) dark-toned supplies (middle of mosaic); and (E1) Newport Ledge, (E2) AEGIS publish 1685a, (E3) Sugarloaf Mountain, three skinny planar laminated dark-toned sandstones. Picture credit score: NASA / Caltech-JPL / MSSS.

“It’s troublesome for manganese oxide to kind on the floor of Mars, so we didn’t anticipate finding it in such excessive concentrations in a shoreline deposit,” Dr. Gasda stated.

“On Earth, a lot of these deposits occur on a regular basis due to the excessive oxygen in our environment produced by photosynthetic life, and from microbes that assist catalyze these manganese oxidation reactions.”

“On Mars, we don’t have proof for all times, and the mechanism to provide oxygen in Mars’ historic environment is unclear, so how the manganese oxide was fashioned and concentrated right here is admittedly puzzling.”

“These findings level to bigger processes occurring within the Martian environment or floor water and exhibits that extra work must be finished to know oxidation on Mars.”

To measure manganese abundances in lakebed rocks inside Gale crater, Dr. Gasda and co-authors used the ChemCam instrument onboard NASA’s Curiosity rover.

“ChemCam is an atomic emission spectroscopy instrument that makes use of laser-induced breakdown spectroscopy (LIBS) to quantify elemental abundances current in a goal,” they defined.

“The ChemCam LIBS makes use of a pulsed laser emitting a 1,067 nm beam that’s centered onto a goal as much as 7 m from the rover, which produces an analytical footprint of 350-550 μm.”

“Every laser pulse ablates and ionizes a small (nanograms to micrograms) quantity of fabric.”

“Gentle emitted from the plasma fashioned by every laser pulse is collected by the ChemCam telescope, and spectra are recorded by the ultraviolet, violet, and visual to close infrared spectrometers.”

The sedimentary rocks explored by the Curiosity rover are a mixture of sands, silts, and muds.

The sandy rocks are extra porous, and groundwater can extra simply go via sands in comparison with the muds that make up many of the lakebed rocks in Gale crater.

The researchers checked out how manganese may have been enriched in these sands — for instance, by percolation of groundwater via the sands on the shore of a lake or mouth of a delta — and what oxidant could possibly be accountable for the precipitation of manganese within the rocks.

On Earth, manganese turns into enriched due to oxygen within the environment, and this course of is usually sped up by the presence of microbes.

Microbes on Earth can use the various oxidation states of manganese as power for metabolism; if life was current on historic Mars, the elevated quantities of manganese in these rocks alongside the lake shore would have been a useful power supply for all times.

“The Gale lake surroundings, as revealed by these historic rocks, provides us a window right into a liveable surroundings that appears surprisingly much like locations on Earth at present,” stated ChemCam principal investigator Dr. Nina Lanza, a researcher at Los Alamos Nationwide Laboratory.

“Manganese minerals are widespread within the shallow, oxic waters discovered on lake shores on Earth, and it’s exceptional to search out such recognizable options on historic Mars.”

The group’s paper was printed within the Journal of Geophysical Analysis: Planets.

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P.J. Gasda et al. 2024. Manganese-Wealthy Sandstones as an Indicator of Historical Oxic Lake Water Circumstances in Gale Crater, Mars. JGR: Planets 129 (5): e2023JE007923; doi: 10.1029/2023JE007923

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